The E(%) -pH curves of the ternary surface complexes at liquid-solid interfaces in the simulated seawater system of a-FeOOH-Cu(II) -tryptophan were determined. The diffuse reflectance IR spectra of the species at the solid surfaces in the above ©S©L©M (Type II), ternary equilibration system were exa
Studies of Ternary Surface Complexes at Liquid–Solid Interfaces in Sea Water by theE(%)–pH Curve Method
✍ Scribed by Zhang Zhengbin; Liu Liansheng; Zhao Hongbin; Fu Youjun; Wu Zhijian
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 206 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0021-9797
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✦ Synopsis
covered during the past 20 years. Studies of the ternary A new method to study ternary surface complexes at liquidsurface complexes in natural water (including sea water) solid interfaces, the E(%) -pH curve method, is proposed. Three are receiving increasing interest. 2 types of E(%) -pH curves, namely left-right shifts of S-shaped Ternary surface complexes were divided into two types curves, V-shaped curves, and monodirectionally shifted curves, by Schindler and co-workers (1-4):, are postulated. Correspondingly, in addition to the Type I ternary surface complex S-O-M-L S-O-M-L (I) S-L-M, [1] (II) and the Type II ternary surface complex and into three types by Davis and Leckie (5), S-L-M, a new type of ternary surface complex,
📜 SIMILAR VOLUMES
This article suggests a new method of determining the stability constant of ternary coordination complexes at liquid-solid interfaces in natural water. Its basic principle is based on the rule of left-right shift of an S-type curve, from which the ''volcano'' curve of exchange ratio E(%) vs concentr