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Studies of stabilized low temperature ignition II—Acetaldehyde and propene
✍ Scribed by J.F. Griffiths; G. Skirrow; C.F.H. Tipper
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 427 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0010-2180
No coin nor oath required. For personal study only.
✦ Synopsis
Some further results on the stabilized low temperature ignition of acetaldehyde have been oOtained. The addition of formaldehyde increases the induction period to the cool flame but reduces the time betweex: the cool and second stage flames. Stabilization of ignition of propene--oxy ~,en mixtures was achieved by the addition of small amounts of acetaldehyde. Composition profiles through cool ard second stage flames in this system show that the products included propene oxide, acrolein, methanol, ethano, formaldehyde and hydrocarbons such as methane, ethylene and butene. Oxidation of the propene also gave rise to further acetaldehyde, which was an important intermediate being a source of methyl radicals.
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the radical oxy-Cope rearrangement. [17] For this purpose, the sulfoxide 10 was prepared from norbornenone 8 via the allylic alcohol 9 (the direct synthesis with the procedure of Evans et al. does not work in this particular case). By treating the sulfoxide 10 with Bu 3 SnH and azobisisobutyronitril