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Studies of ruthenium(IV) and its reduction products in perchlorate solutions

✍ Scribed by Wallace, Richard M.; Propst, Robert C.

Book ID
121332986
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
843 KB
Volume
91
Category
Article
ISSN
0002-7863

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The electrochemical reduction of rutheni
The electrochemical reduction of ruthenium(IV) in perchloric acid solutions on platinum electrodes
✍ J. Schauwers; F. Meuris; L. Heerman; W. D'Olieslager πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 611 KB

Two reversible wavesare observed for the reduction of Ru(IV) on platinum electrodes. Each wave is the sum of two one-electron steps according to: 1st wllve Ru,(OH):: (IV)-Ru4(0H)$ (3,75)=Ru,(OH):+ (3.5) 2nd wave /wv-l Ru,(OH);+ (3,S)=Ru,(OH);+ (3.25)= Ru+(OH):+ (III) k, 4 stable Ru(II1) Potentials (