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Studies of rotational relaxation in thioformaldehyde by radiofrequency-optical double resonance

✍ Scribed by J.C. Petersen; D.A. Ramsay


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
317 KB
Volume
118
Category
Article
ISSN
0009-2614

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✦ Synopsis


Radlofrequmcy

-optical double resonance is used to momtor collisional relaxation hm various J, levels in the ,&'A,, u,, = 1 state or thloformaldehyde to the 16, levels. The results indicate lhat changes of J up to +. 12 and or K, = f 2 can occur m one or at most a kw collistons. ' R-h Associalc 198%198%

gest that the technique could have widespread applications and yield quantitative measurements on rotational relaxation processes.


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## Microwave -optical double resonance experiments have been camed out on the 4; band of the A 'AZ-R 'At system of thioformaldehyde &CS). More than 100 microwave and radiofrequency transitions have been observed in the ii ' A2 excited state. Many of these transitions are magnetically sensitive. So

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