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Studies of platinum electroplating baths: Part II. Deposition of platinum from a solution of Pt(H2O)42+ in aqueous acid

✍ Scribed by Adrian J. Gregory; William Levason; Derek Pletcher


Publisher
Elsevier
Year
1993
Tongue
English
Weight
538 KB
Volume
348
Category
Article
ISSN
1572-6657

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking