✦ LIBER ✦

Studies of oxidation processes leading to ignition of butanes, butenes and cyclobutane

✍ Scribed by K.C. Salooja

Publisher: Elsevier Science
Year: 1967
Tongue: English
Weight: 505 KB
Volume: 11
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(67)90021-1

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✦ Synopsis

The extent of overall reaction at various +.¢tnpcratult.'+, preceding tgllllIOI1, and the k..,nilion ¢.+lara¢lcri~tiex+ of butane, isobulane, hut-I-eric, cis-but-2-¢ne, o'ans-but-2-cne, ~ohutcnc ,tnd cxclobutan¢ ha+,e ~'cn sit, died under identical extx'rimcnlat conditions. Analyst~ of the ma0or cdrbonyl, h)droxyl and hydrocarbon inter-mediat~.~ tona,xl at dill}rent pre-tlam¢ stag~,s of the hydroca: bon~ hax c at~ ~ccn made+

The rctalix'c order of reactivity of some of the hydrt~:arhons l.~ difk'tcnt from that rcport<.at by other workers: but-I-eRe is more reactive than the but-2-cncs, ri.+-but-2-cnc being .,lightly more rcac:i~c than tv, w.+-but-2-cnc. an',t isobutane ~ ,,'cry much mort' rcacm c than isobutenc. The.,c rc.~ults. ,a ith |hi' inforn,ation from the analytical studiem provide a ~lisfactot 3' understanding of the nlc¢~:mt~,m of ¢ombtt~,ti,t,lt of the hydrt~:arbom, studi~.xl.

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