The crystal structure of di-pcthoxy-bis(dibenzy1ethox y-titaniurn(IV)), r(EtO),'Ci-(CHgPh)B]B, has been determined from analysis of photographic X-ray data. Thc crystal system is monoclinic, a = 7.93(2), b = 15.99(2), c = 13.40(2) A, p = 92.7(3)", space group PZ,/c. Tho molecule is a dimcr situated
✦ LIBER ✦
Studies of Organometallic Compounds XV. The Crystal Structure of Bis(tribenzyl-titanium(IV))-μ-oxo
✍ Scribed by Helen Stoeckli-Evans
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- German
- Weight
- 338 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The crystal and molecular structure of bis(tribenzyl‐titanium(IV))‐μ‐oxo, [(PhCH~2~)~3~‐Ti]~2~O, has been determined from analysis of X‐ray photographic data. The crystal system is rhombohedral, a = 9.58(2) Å, α = 83.6(2)°, space group __R__3, Z = 1.
📜 SIMILAR VOLUMES
Studies of Organometallic Compounds XVI.
✍
Helen Stoeckli-Evans
📂
Article
📅
1975
🏛
John Wiley and Sons
🌐
German
⚖ 351 KB
Organometallic Compounds of the Lanthani
✍
Herbert Schumann; Markus R. Keitsch; Jörg Demtschuk; Stefan Mühle
📂
Article
📅
1998
🏛
John Wiley and Sons
🌐
German
⚖ 171 KB
👁 2 views
The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4