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Studies of molybdenum thiolato-complexes. The chemical characterization and the crystal and molecular structures of two sulphido-bridged Movdimers, [PhCH2PPh3]2[Mo2O2S2(SC2H4S)2] and [HNEt3]2[Mo2S4(SC2H4S)2]

✍ Scribed by Tze-Chen Hsieh; Kassu Gebreyes; Jon Zubieta


Publisher
Springer
Year
1985
Tongue
English
Weight
382 KB
Volume
10
Category
Article
ISSN
0340-4285

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure