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Studies of molecular ions. IX. Detection of low-lying ‘non-Koopmans’ states in polyacetylene molecular cations

✍ Scribed by Edwin Haselbach; Urs Klemm; Urs Buser; Rudolf Gschwind; Martin Jungen; Else Kloster-Jensen; John P. Maier; Oscar Marthaler; Heniz Christen; Peter Baertschi


Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
471 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Comparison of the photoelectron spectra of the title compounds with the electronic absorption spectra of the corresponding radical cations led to the detection of low lying ‘Non‐Koopmans’‐states in the ionic species.