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Studies of Inclusion Complexes of Dichloromethane in Cryptophanes by Exchange Kinetics and 13C NMR in Solution and the Solid State

✍ Scribed by Aski, S. Nikkhou; Lo, A. Y. H.; Brotin, T.; Dutasta, J. P.; Edén, M.; Kowalewski, J.

Book ID
111980165
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
147 KB
Volume
112
Category
Article
ISSN
1932-7447

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Inclusion complexes of cryptophane–E with dichloromethane and chloroform: A thermodynamic and kinetic study using the 1D-EXSY NMR method
✍ Sahar Nikkhou Aski; Zoltan Takacs; Jozef Kowalewski 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB

## Abstract Complexation equilibria and kinetics of exchange of chloroform and dichloromethane molecules between the cavity of cryptophane‐E and bulk solution were investigated using NMR methods. Using one‐dimensional magnetization transfer (1D‐EXSY type sequence), chemical exchange rates were meas