Studies of absolute rate coefficients in alternating copolymerization by observation of pre- and after-effects

Non-stationary states in free-radical po

Non-stationary states in free-radical polymerizations with size-dependent termination. Studies by the group-termination procedure—3. Further consideration of after-and pre-effects and evaluation of absolute coefficients

✍ C.H. Bamford 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 486 KB

Al~traet--In earlier studies of the kinetic quantities in non-stationary stages of non-classical free-radical polymerization a relation between the total pre-and after-effects (AMos, AM~, respectively) and the rate coefficients kp kto was proposed. This arose from the results of numerical computatio