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Studies of a new series of ion-pair complexes [Mo(dtc)4][Ln(dtc)4] (Ln = La-Er, exp. Pm)

✍ Scribed by Fu Qing-Hong; Zhang Guang-Ren; Sun Chun-Ting; Niu Shu-Yun; Wu Li-Xin


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
278 KB
Volume
14
Category
Article
ISSN
0256-7660

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✦ Synopsis


A new series of ion-pair complexes [Mo(dtc)4][Ln(dtc)l] (Ln=La-Er, exp. Pm) were synthesized from MoCls, LnCls and Nadtc in anhydrous methanol. The crystal structures of the four complexes, [Mo(dtc)4][Ln(dtc)d] (Ln=Nd, Sm, Ho and Er) have been determined by X-ray diffraction.

Spectroscopic properties of all these complexes are also discussed here.