Studies of a Nickel-Based Single-Molecul
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Hanspeter Andres; Reto Basler; Alexander J. Blake; Cyril Cadiou; Gregory Chabous
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Article
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2002
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John Wiley and Sons
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English
โ 223 KB
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A cyclic complex [Ni(12)(chp)(12)(O(2)CMe)(12)(thf)(6)(H(2)O)(6)] (1) has been synthesised and studied (chp=6-chloro-2-pyridonate). Complex 1 exhibits ferromagnetic exchange between the S=1 centres, giving an S=12 spin ground state. Detailed studies demonstrate that it is a single-molecule magnet wi