𝔖 Bobbio Scriptorium
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Studies into the constitution of aluminium isopropoxide

✍ Scribed by J.G. Oliver; P.K. Phillips; I.J. Worrall


Book ID
118907551
Publisher
Elsevier Science
Year
1969
Weight
169 KB
Volume
31
Category
Article
ISSN
0022-1902

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Highly regio and chemoselective ring ope
✍ Kun I. Sutowardoyo; Mohamed Emziane; Paul Lhoste; Denis Sinou πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 922 KB

The ring-opening of functionalized epoxides with trimethylsilyl azide in the presence of a catalytic amount of Ti(O-i-l%)4 or Al@-i-F?)3 is described. The reaction is stereo8pecific and highly regiospecific, leading generally to the formation of the carbon-azido bond on the less substituted carbon.