STUDIES IN THE THIOPHENE SERIES. VI. AZLACTONES AND RHODANINES PREPARED FROM 2-THENALDEHYDE AND SOME SUBSTITUTED 2-THENALDEHYDES 1
✍ Scribed by CROWE, BERNARD F.; NORD, F. F.
- Book ID
- 121427656
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 448 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
In addition to the parent compounds, nine methyl-substituted l,Mibydro-4H-3,l-benzoxazines with and without N-methyl substitution were prepared. The chain tautomer could only be detected in the case of 1,2-dihydro-2+ nitrophenyl)-4H-3,1-benzoxazine in solution. The configurational and conformational
## Abstract Seventeen __N__‐substituted 3,4‐dihydro‐2__H__‐1,3‐benzoxazines [__N__‐substituent = Et, Pr^__i__^, Bu^__t__^, CH~2~C~6~H~5~ or CH(CH~3~)C~6~H~5~] were prepared and their structures studied in the light of ^13^C chemical shifts. The γ effects caused by C(α)‐methyl or C(α)‐phenyl substit