𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies in the Thermal Decomposition of Tertiary Carbamates in Solution

✍ Scribed by Elizabeth A. Jordan; Melanie P. Thorne

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
40 KB
Volume
91
Category
Article
ISSN
0037-9646

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetic study of the decompositions invo
Kinetic study of the decompositions involved in the thermal degradation of commercial azodicarbonamide
✍ J. A. Reyes-Labarta; A. Marcilla 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

## Abstract The transitions and reactions involved in the thermal treatment of several commercial azodicarbonamides (ADC) in an inert atmosphere have been studied by dynamic thermogravimetry analysis (TGA), mass spectrometry and Fourier transform infrared (FTIR) spectroscopy. A pseudo‐mechanistic m

Thermal Decomposition of 1,2-Oxathiolane
Thermal Decomposition of 1,2-Oxathiolane in the Gas Phase
✍ Carlsen, Lars ;Egsgaard, Helge 📂 Article 📅 1984 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 293 KB

## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium