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Studies in the synthesis of retinoids II. Acetylation of C20diolyne and C20diol

โœ Scribed by E. L. Deryabina; R. L. Vasil'eva; B. I. Deineka


Book ID
112405468
Publisher
Springer
Year
1992
Tongue
English
Weight
234 KB
Volume
26
Category
Article
ISSN
0091-150X

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Synthetic studies toward phorboxazole A.
โœ David R Williams; Michael P Clark; Martin A Berliner ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 250 KB

A stereocontrolled synthesis of two fragments comprising the macrocyclic core of Phorboxazole A is described. The C3-C19 bis-pyran segment is prepared utilizing reiterative enantioselective allylations from homochiral aUylstannanes followed by stereoselective cyclizations. The pentasubstituted tetra