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Studies in the allo- and isoalloxazine series. XII. New synthesis of 7-chloroalloxazine

✍ Scribed by V. M. Berezovskii; G. D. Glebova

Book ID
112490731
Publisher
Springer US
Year
1965
Tongue
English
Weight
152 KB
Volume
1
Category
Article
ISSN
0009-3122

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NMR.-Study of Nitrogen Inversion and Con
NMR.-Study of Nitrogen Inversion and Conformation of 1,5-Dihydro-isoalloxazines (β€˜Reduced Flavin’). Studies in the flavin series, XIX. Communication
✍ Ludwig Tauscher; Sandro Ghisla; Peter Hemmerich πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 935 KB

## Abstract The pyramidal inversion of the N(5)‐centre of several reduced flavins was measured by NMR. The inversion barrier was found to be ∼10 kcal/mol in acetone solutions and to be independent of the size of the N(5) substituent. An increase of the inversion barrier of ∼5 kcal/mol was observed