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Studies in Stereochemistry. XXX. Models for Steric Control of Asymmetric Induction 1

✍ Scribed by Cram, Donald J.; Kopecky, Karl R.


Book ID
120347088
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
929 KB
Volume
81
Category
Article
ISSN
0002-7863

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## Abstract The barriers to rotation of the 3‐substituent in six 3‐RCH~2~‐4‐Me‐δ^4^‐thiazoline‐2‐thiones (R ο£Ύ Me, Et, Pr, Isobu, Isopr,__t__‐Bu) and in two analogous methiodides have been measured by the ^1^H DNMR technique. The barriers are discussed in relation to the possible conformations of th