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Studies in some new initiator systems for vinyl polymerization. II. Ammonia–halogen system as the redox initiator

✍ Scribed by Pramanick, Dinabandhu ;Palit, Santi R.


Publisher
Wiley (John Wiley & Sons)
Year
1968
Tongue
English
Weight
306 KB
Volume
6
Category
Article
ISSN
0449-296X

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The kinetics of aqueous polymerization of acrylonitrile initiated by peroxomonosulphate-Co(II) redox system have been investigated in the range 30-50°C under nitrogen at a fixed ionic strength of 0.30mol-dm -3. The overall rate of polymerization, followed gravimetrically, was found to be proportiona