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Studies in ring-opening polymerization—XII. The ring-opening polymerization of oxetane to living polymers using a porphinato-aluminium catalyst

✍ Scribed by A.J. Amass; M.C. Perry; D.S. Riat; B.J. Tighe; E. Colclough; M.J. Stewart


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
369 KB
Volume
30
Category
Article
ISSN
0014-3057

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Understanding the Ring-Opening Reaction
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## Abstract The primary‐amine‐initiated polymerization of __α__‐amino acid __N__‐carboxyanhydride (NCA) is a widely‐used and promising way to synthesize polypeptide‐involved materials with various applications. The nucleophilic attack mechanism, also known as normal amine mechanism of ring opening