𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies in organosilicon chemistry: XLV. The addition of certain organosilicon compounds to ketene

✍ Scribed by William W. Limburg; Howard W. Post

Book ID
104586477
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
213 KB
Volume
81
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Nine organosilicon compounds containing OH or NH have been found to add to ketene. Three carbon functional primary alcohols add to give acetates. Four primary amines and one secondary amine form N‐substituted acetamides while butyl‐trimethylsilyalmine yields N‐butyltrimethylsilylacetamide.

📜 SIMILAR VOLUMES

Studies in organosilicon chemistry. XLII
Studies in organosilicon chemistry. XLII. Reactions of certain silylbenzaldehydes in concentrated base
✍ Thomas J. Maass; Howard W. Post 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 264 KB

## Abstract A crossed Cannizzaro reaction using formaldehyde with __m__‐trimethylsilylbenzaldehyde and __p__‐trimethylsilylbenzaldehyde yields mostly the benzyl alcohol derivative. No formic acid was detectable but a small amount of the substituted benzoic acid was isolated. The corresponding triph