Studies in organophosphorus chemistry III. Structures of tertiary phosphine dihalides in solution

✍ Scribed by G.A. Wiley; W. R. Stine

• Publisher: Elsevier Science
• Year: 1967
• Tongue: French
• Weight: 186 KB
• Volume: 8
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)90821-9

✦ Synopsis

Tertiary phospbine dihalides &PXs)

are efficient reagents for alkyl halide synthesis by virtue of having only two replaceable groups on "pentavalent" phosphorus

( 3) . Previous attempts at determining the structures of these substances have had limited success (4) . We report here the solution to this problem.

2,

1360 (1964). (9) K. Moedritzer and J . R. Van Wazer, Inorg. Chem. , f, 139 (1964). (10) L. Kolditz and D. Hass, Z. Anorg. v. Allgem. Chem., z, 191 (1958).