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Studies in organometallic rearrangements V. Substituent effects on the fluxional rearragements and isomerization of indenyl silanes and stannanes

✍ Scribed by M.N. Andrews; P.E. Rakita; G.A. Taylor

Book ID
114041028
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
736 KB
Volume
13
Category
Article
ISSN
0020-1693

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Substituent effects on the fluxional rea
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✍ M.N. Andrews; P.E. Rakita; G.A. Taylor πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 156 KB

Recent studies have shown that the monohqto indenyl compounds (I) of a number of main group and transition series metals exhibit dynanic intramolecular (fluxional) rearrangements.' In the case of the indenylsilanes (Ia) a kinetically slower hydrogen migration occurs, giving rise to non-fluxional pos

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## Abstract We have performed ab initio molecular orbital calculations on 1‐ and 2‐substituted propenes, acetaldimines, and aldehydes β€” H~3~CC(X)=Y and XCH~2~CH=Y (Y = CH~2~, NH, O; X = H, CH~3~, NH~2~, OH, F) β€” to investigate the effects that substituents and functional groups have on their isoele