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Studies in Organic Sulfur Compounds. IX. 1 Preparation and Desulfurization of Optically Active 1,1-Diphenyl-3-mercaptopropan-2-ol 2

✍ Scribed by Djerassi, Carl; Grossman, J.


Book ID
126775590
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
397 KB
Volume
79
Category
Article
ISSN
0002-7863

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## Abstract Oxindole 11, obtained on 3‐[2′‐(dimethylamino)ethyl]alkylation of oxindole 12, yielded, on stereoselective reduction with sodium dihydridobis(2‐methoxyethoxy)aluminate, aminoalcohol 8 (__Scheme 2__). The quaternary methiodide 10, obtained from 8 with MeI, gave, in nucleophilic displacem