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Studies in Lipase Catalyzed Transesterifications: Synthesis of (+)-Albicanol, (+)-Albicanyl Acetate and Chiral Intermediates Useful in the Synthesis of Drimanes and Labdanes

✍ Scribed by A.T Anilkumar; Uma Sudhir; S Joly; Mangalam S Nair

Book ID: 104202559
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 118 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00096-x

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✦ Synopsis

Chiral intermediates [(Ϫ)-8, (ϩ)-9, (Ϫ)-9, (ϩ)-10, (Ϫ)-10, (ϩ)-11] useful in the synthesis of drimanes and labdanes, as well as optically active albicanol 1 and albicanyl acetate 2, have been synthesized using enzymatic transesterification as the key step.

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