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Studies in claisen rearrangement a Novel transformation of δ -aryloxymethyl acrylic acid

✍ Scribed by B. Gopalan; K. Kajagopalan; S. Swaminathan; K.K. Balasubramanian


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
122 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis


In connection with our study on the competitive Claieen vs Fries reexrsngement of sryld.-aryloxymethyl acrylates2, we investigated the acid catalysed


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Studies in claisen rearrangement - novel
✍ G.V.Bindu Madhavan; K.K. Balasubramanian 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 710 KB

The thermal rearrangement of 2,4-di(N-aryl)amino-1,3,5-triazin-6yl-prop-2-ynyl ethers 6-methyleneimidazo(l,2-a)-1,3,5-triar + yield a mixture of ne4-one & and 6-methylimidazo(l,2-a)-1,3,5-triazine-4-one 1, whereas under the influence of mercuric trifluroacetate the ethers 3 yield only 9. at room tem