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Studies in aromatic nitration. 2. Nitrogen-14 NMR study of the nitric acid/nitronium ion equilibrium in aqueous sulfuric acid

✍ Scribed by Ross, David S.; Kuhlmann, Karl F.; Malhotra, Ripudaman


Book ID
125488364
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
414 KB
Volume
105
Category
Article
ISSN
0002-7863

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## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β€…1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ”[Mn^IV^]/Ξ”