Studies in alkylation of 3-methyl-3-sulfolene and thermolysis of resulting 2-alkyl-3-sulfolenes: Convenient synthesis of 1,2-disubstituted-1,3-dienes
✍ Scribed by Shailesh R Desai; Vinayak K Gore; T Mayelvaganan; R Padmakumar; Sujata V Bhat
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 552 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The retro-sulfolene reaction, which thermally produces 1,3-dienes from 2,5-dihydrothiophene-l,l-dioxides, is of considerable practical importance 1,2 interest. 3
## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1
## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1
## Abstract For Abstract see ChemInform Abstract in Full Text.