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Studies Directed toward the Synthesis of Cryptoheptine

✍ Scribed by Zhang, Pingsheng; Bierer, Donald E.


Book ID
120308827
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
56 KB
Volume
63
Category
Article
ISSN
0163-3864

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Studies directed toward the synthesis of
✍ Yonghai Chai; Zonghong Mou; Matthias C. McIntosh πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 427 KB

The fully substituted hydroisobenzofuran core of the massileunicellins containing eight contiguous stereocenters was prepared in 12 steps from (S)-(+)-carvone. Noteworthy elements of the synthesis include a one-step oxidative rearrangement/epoxidation, a novel stereoselective directed reduction of a