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Studies Directed toward Synthesis of the Structure Proposed for Stereocalpin A

✍ Scribed by Yixian Huang; Prof. Dr. Yikang Wu

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 140 KB
Volume: 29
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.201190221

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✦ Synopsis

Some synthetic efforts directed to the proposed structure of stereocalpin A are disclosed. The stereogenic centers in the aldol unit were installed using the method of Evans and the intermediates obtained through a reliable route helped to reveal that the spectroscopic data reported earlier in the literature for the same structures were either erroneous or irrelevant.

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