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Structures of two gold(I) complexes with tricyclohexylphosphine: [(Cy3P)AuCl] and [(Cy3P)2Au]+.Cl−

✍ Scribed by Muir, J. A. ;Muir, M. M. ;Pulgar, L. B. ;Jones, P. G. ;Sheldrick, G. M.


Book ID
114503047
Publisher
International Union of Crystallography
Year
1985
Tongue
English
Weight
312 KB
Volume
41
Category
Article
ISSN
0108-2701

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✍ Holger Braunschweig; Katrin Gruss; Krzysztof Radacki 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 289 KB

## Abstract **A platinum–beryllium adduct** (see structure) was prepared by the reaction of [Pt(PCy~3~)~2~] and BeCl~2~. Treatment with methyllithium resulted in ligand substitution at the beryllium center. Both complexes were structurally characterized and display unprecedented two‐center two‐elec