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Structures of the reduced niobium oxides Nb12O29 and Nb22O54

โœ Scribed by T. McQueen; Q. Xu; E.N. Andersen; H.W. Zandbergen; R.J. Cava


Book ID
104029971
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
898 KB
Volume
180
Category
Article
ISSN
0022-4596

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(Mo, \(\mathrm{Nb})_{13} \mathrm{O}_{33}\) crystallizes in the triclinic system, space group \(P 1\) (No. 2). The unit cell dimensions are \(a=3.8194(4) \AA, b=\) \(11.2898(7) \AA, c=14.9764(9) \AA, \alpha=94.039(5)^{\circ}, \beta=97.326(6)^{\circ}\), \(\gamma=99.748(7)^{\circ}, V=628.47(9) \AA^{3}\

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The electronic structure of Nb 12 O 29 , the 5rst member of the NbO 2.5ุŠx (04x40.083) family of phases, has been studied. It is suggested that in order to understand the coexistence of antiferromagnetism and metallic conductivity in this phase a new crystal structure determination is needed.