Structures of lanthanide complexes of ?-ketophosphoryl compounds
β Scribed by Babecki, Ryszard; Platt, Andrew W. G.; Fawcett, John
- Book ID
- 120020596
- Publisher
- The Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 852 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1472-7773
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π SIMILAR VOLUMES
The determination of solution structure of small to medium size chiral lanthanide complexes through paramagnetic NMR and circular dichroism is briefly reviewed. The main focus is on ytterbium as the rare earth, because of its negligible contact contribution to the hyperfine shift and of its intense
## Abstract Four new disulfoxideβLn^III^ complexes, [Ln(L)~2~(NO~3~)~3~]__~n~__ {Ln = La (1), __n__ = __n__; Ln = Gd (2), Dy (3) and Yb (4), __n__ = 2}, have been prepared by the reaction of Ln(NO~3~)~3~Β·__n__H~2~O with __meso__β1,3βbis(ethylsulfinyl)propane (__meso__βL) in methanol/triethylorthofo