Ah initio molecular orbital calculations with split-valence plus polarization basis sets and incorporating electron correlation and zero-point energy corrections have been used to examine possible equilibrium structures on the [C2H7N]+' surface. In addition to the radical cations of ethylamine and d
Structures of gas phase C5H8 radical cations: A collisional ionization study
โ Scribed by Chhabil Dass; David A. Peake; Michael L. Gross
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 738 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1076-5174
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The kinetics of the gas-phase dehydrogenation of cyclopentane to cyclopentene is found to be consistent with a slow attack by a n I atom (step 4, text) on cyclopentane in the range 282-382OC. The measured rate constants fit the Xrrhenius equation, log k, = 11.95 f 0.08 -(24.9 f 0.23)/0 1 mole-l sec-
The structures of gas-phase [C4H601+' radical cations and their daughter ions of composition [C2H20]+' and [C,H,]+' were investigated by using collisionally activated dissociation, metastable ion measurement, kinetic energy release and collisional ionization tandem mass spectrometric techniques. Ele