Structures of carbanions, I. Solvent control of product geometries from O-phosphorylation of enolate anions

Structures of carbanions, II. Effects of

Structures of carbanions, II. Effects of cation, concentration and solvent upon the geometries of reactions of enolate anions

✍ Bernard Miller; Howard Margulies; Thomas Drabb Jr.; Richard Wayne 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 198 KB

In the preceding paper' we reported that 0-phosphorylation of the potassium enolatee of a variety of substituted ketones gave mixtures consisting predaainantly of cis-isomers2 from re-action in non-polar solvents and predominantly of trans-isomers 2 from reaction in polar solvents. Formation of cis