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Structures of [(C2H5)4N]2[In2Fe6(CO)24] and [(C2H5)4N][(2,2'-bipyridine)InFe2(CO)8]

✍ Scribed by Cassidy, J. M. ;Whitmire, K. H.

Book ID: 114507221
Publisher: International Union of Crystallography
Year: 1990
Tongue: English
Weight: 607 KB
Volume: 46
Category: Article
ISSN: 0108-2701
DOI: 10.1107/s0108270190000026

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## Abstract The cobaltocenium salts [Co{C~5~H~4~(B__i__Pr~2~)}~2~]PF~6~ [(1a)PF~6~] and [Co{C~5~H~4~(BMe~2~)}~2~]PF~6~ [(1b)PF~6~] are strong Lewis acids. With pyridine (1a)PF~6~ forms a mono‐adduct 2 and a di‐adduct 3 which show NMR spectra in the low‐temperature regime of pyridine exchange. With