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Structures of Becton's [Pt(NH3)4CuCl4] and Millon's [Cu(NH3)4PtCl4] salts

โœ Scribed by Morosin, B. ;Fallon, P. ;Valentine, J. S.

Book ID
117859726
Publisher
International Union of Crystallography
Year
1975
Weight
491 KB
Volume
31
Category
Article
ISSN
0567-7408

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The formation of the title compounds by reaction of copper with yellow ammonium sulphide solutions is investigated. The new compound NIf,Cu,S, is isotypic to KCu,S, (space group P4/mmm, a = 3.907 A, c = 9.453 A) The topotactic decomposition of NI-I,Cu,S, to digenite between 120-140ยฐC is studied and