Structures of 6a-thia/selena-1,3,4,6-tetraazapentalene derivatives: hypervalent S/Se–N bonds
✍ Scribed by Iwasaki, F. ;Murakami, H. ;Yamazaki, N. ;Yasui, M. ;Tomura, M. ;Matsumura, N.
- Book ID
- 114507859
- Publisher
- International Union of Crystallography
- Year
- 1991
- Tongue
- English
- Weight
- 649 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0108-2701
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## 3-Methy1-6,7-dihydrc~-SH-l, 2,4-th iadiazolo[4,5-a] pyrimidine 4a reacted with isocyanates and isothiocyanates with elimination of acetonitrile and concomitant addition of two molecules of the heterocumubne togive the2,3-disubstituted-6,7-dihydro-SH-2ah4-thia-2, 3, 4a, ia-tetraazacyclopent[cd]