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Structures, Electronic Properties, and Oxidation-Reduction Reactivity of Halogenated Iron Porphyrins

✍ Scribed by Grinstaff, Mark W.; Hill, Michael G.; Birnbaum, Eva R.; Schaefer, William P.; Labinger, Jay A.; Gray, Harry B.

Book ID
126803354
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
751 KB
Volume
34
Category
Article
ISSN
0020-1669

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✍ Eva R. Birnbaum; Mark W. Grinstaff; Jay A. Labinger; John E. Bercaw; Harry B. Gr πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 361 KB

The halogenated Porphyrin, 2,12,13,17,l5,~~hy~nat~iron(III) chloride, [ Fe( TPPPBr,)Cl] , catalyzes the oxidation of cyclohexene in the presence of molecular oxygen or iodosobenzene. With PhIO, 77% epoxide is observed, consistent with a mechanism involving a high-valent metaI-oxo species. With dioxy