The spectroscopic properties (i.r., NMRIH and 13C) of substituted N-methyl 2H-3,4 dihydro 1,3-benzoxazines has been studied. Infrared and NMR~H data allow to determine structures of isomers and NMR~3C exhibits electronic and steric effects of substituents.
✦ LIBER ✦
Structures de modeles de polyesters—I. Separation et etude par RMN [13C]des dihydroxy-2,3 butane, 2,4 pentane et 2,5 hexane et de leurs benzoates
✍ Scribed by M.F. Grenier-Loustalot; P. Grenier
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 395 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0014-3057
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The condensation of (1 R,2S) or (lS,2S)-N,N'-dimethyI-l-phenylpropane-l 2-diamines with aldehydes gives respectively two diastereorneric 2-alkyl-l,3,4-trimethyI-S-phen limidazolidines. At thermodynamical equilibrium the major isomer in the erythro series is this one where t f ! e substituents at pos