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Structure–reactivity correlations of benzoin alkyl ethers. Structures of 2-methoxy-1,2-diphenylethanone (I) and 2-isopropoxy-1,2-diphenylethanone (II)

✍ Scribed by Kanagapushpam, D. ;Ramamurthy, V. ;Venkatesan, K. ;Cameron, T. S. ;Linden, A.


Book ID
114505268
Publisher
International Union of Crystallography
Year
1988
Tongue
English
Weight
532 KB
Volume
44
Category
Article
ISSN
0108-2701

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Reactions of 2,5-dilithiated 1-methylpyrrole (1a) with the aryloxy-boryl derivative 2e. Reacting monolithiated 1methyl-and 1-benzylpyrroles with Cl 2 BNiPr 2 yields the di(2-ClB(NR 2 ) 2 lead to the novel 2,5-diboryl-1-methylpyrroles 2a and 2b. Accordingly, 2,5-diboryl-1-benzylpyrrole 2d is pyrrolyl