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Structure–performance relationship in Ziegler–Natta olefin polymerization with novel core–shell MgO/MgCl2/TiCl4 catalysts

✍ Scribed by Toshiaki Taniike; Patchanee Chammingkwan; Minoru Terano

Book ID: 116343934
Publisher: Elsevier Science
Year: 2012
Tongue: English
Weight: 383 KB
Volume: 27
Category: Article
ISSN: 1566-7367
DOI: 10.1016/j.catcom.2012.06.015

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The FT-Raman spectra of a series of mechanically prepared MgCl 2 -TiCl 4 samples with increasing content of TiCl 4 have been recorded. Raman scattering lines in the range 600-100 cm -1 reveal the formation of TiCl 4 molecules complexed on the lateral cuts of activated MgCl 2 crystals. This pattern o