Structured emission of tetrahedral complexes due to Jahn-Teller and pseudo-Jahn-Teller effects
✍ Scribed by Bacci, M.; Porcinai, S.; Mihóková, E.; Nikl, M.; Polák, K.
- Book ID
- 119958525
- Publisher
- The American Physical Society
- Year
- 2001
- Tongue
- English
- Weight
- 226 KB
- Volume
- 64
- Category
- Article
- ISSN
- 1098-0121
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We present a theoretical account of the Jahn-Teller (JT) and pseudo-Jahn-Teller (PJT) effects in the photoelectron spectrum of cyclopropane. The PJT interactions between the two JT split X 2 E 0 and Ã2 E 00 electronic states of the cyclopropane radical cation are examined. Nuclear dynamical simulati
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The correlation between the solvent dependence of thhc spectral shape of fluorescence and the solvent dcpcndencu of the radintionlcss trzlnsitions strongly suggcets that it is the pseudo Jahn-Tcllcr distortions of the lowest excited singlet state which lends to the strong solvcnt dependence of the f