Ruthenium supported on y-alumina modified with KOH was tested as catalyst for ammonia synthesis under atmospheric pressure. Ru3(CO)~2 and RuC13 were compared as ruthenium precursors. The catalysts derived from Ru3(CO)12 exhibited an up to five times higher productivity than the corresponding ones de
✦ LIBER ✦
Structure sensitivity of supported ruthenium catalysts for ammonia synthesis
✍ Scribed by Claus J.H Jacobsen; Søren Dahl; Poul L Hansen; Eric Törnqvist; Lone Jensen; Henrik Topsøe; Dorthe V Prip; Pernille B Møenshaug; Ib Chorkendorff
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 732 KB
- Volume
- 163
- Category
- Article
- ISSN
- 1381-1169
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Based on combination advantages of both supports MgO and carbon nanotubes (CNTs), a novel combination-type catalyst for ammonia synthesis has been developed, in which two catalysts, K-Ru/MgO and K-Ru/CNTs, are combined with the optimal weight ratio of 1/1. The results show that the highest catalytic