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Structure Sensitivity in the Hydrodechlorination of Chlorobenzene Over Supported Nickel

✍ Scribed by Mark A. Keane; Colin Park; Claudia Menini

Book ID: 110438140
Publisher: Springer US
Year: 2003
Tongue: English
Weight: 321 KB
Volume: 88
Category: Article
ISSN: 1011-372X
DOI: 10.1023/a:1023599203073

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The kinetics of the hydrodechlorination (HDC) of chlorobenzene has been measured over Ni supported on a range of substrates (MgO, SiO 2 , Al 2 O 3 , Ta 2 O 5 , MgO, activated carbon (AC) and graphite) of varying BET area (9-843 m 2 g -1 ) where the Ni loading was in the range 1.5-20.3% (w/w) with ca

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The catalytic hydrodechlorination of chlorobenzene with NirC, PdrC and Ni Pd rC in ethanol was studied with 2 D 98 2 13 Ä 1 4 Ž . and C H NMR. Two dechlorination routes of this reaction ionic and free-radical are suggested depending upon the nature of the active hydrogen species. At the same time t