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Structure refinement of barium metavanadate BaV2O6

โœ Scribed by Takeshi Yao; Yoshio Oka; Naoichi Yamamoto


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
245 KB
Volume
238
Category
Article
ISSN
0020-1693

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Ba analogues of hewettite (CaV 6 O 16 โ€ข 9H 2 O) were synthesized by the hydrothermal methods. The compounds exhibit two phases formulated by BaV 6 O 16 โ€ข nH 2 O and Ba 1ุ‰x V 6 O 16 โ€ข nH 2 O (x+0.2, n+3), and the structure of BaV 6 O 16 โ€ข nH 2 O has been determined from a single crystal study. It cry

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The Raman spectra of polycrystalline samples of the metavanadates M"V,O,, (with M = Ca, Cd, Cu and Mg), belonging to the brannerite structural type, have been recorded. A general assignment, supported by comparisons with known vibrational properties of other oxovanadium species, is proposed. The com