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Structure Refinement by the Rietveld Method of the Thiogermanates [(CH3)4N]2MGe4S10(M= Fe, Cd)

✍ Scribed by O. Achak; J.Y. Pivan; M. Maunaye; M. Loüer; D. Loüer


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
288 KB
Volume
121
Category
Article
ISSN
0022-4596

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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =