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Structure-reactivity relationships: the oxidation of aliphatic diols on a gold electrode

✍ Scribed by T. Łuczak; M. Bełtowska-Brzezinska; R. Holze

Book ID
104692347
Publisher
Springer
Year
1993
Tongue
English
Weight
467 KB
Volume
23
Category
Article
ISSN
0021-891X

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Molecular structure effects in the adsor
Molecular structure effects in the adsorption of terminal and vicinal aliphatic diols on a gold electrode
✍ Teresa Łuczak; Maria Bełtowska-Brzezinska; Rudolf Holze 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 425 KB

The adsorption of a series of terminal and vi&al aliphatic diols at a polycrystalline gold electrode from a solution of 0.02 M NaClO, has been studied. Significant trends and differences in the electrosorption behavior clearly related to the molecular structure of the alcohols were found.

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✍ Rudolf Holze; Teresa Łuczak; Maria Bełtowska-Brzezinska 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 461 KB

The electro-oxidation of a series of selectively deuterated alcohols (Zpropanol, 1,2-butanediol, l+butanediol and 2,fbutanediol) at a polycrystalline gold electrode in alkaline solutions was studied with cyclic voltammetry. Results were evaluated with respect to the mechanism of the electro-oxidatio