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Structure-Reactivity Relationships of Methylated Tetrahydrofurans with Lithium

โœ Scribed by Goldman, J. L.

Book ID
121859548
Publisher
The Electrochemical Society
Year
1980
Tongue
English
Weight
871 KB
Volume
127
Category
Article
ISSN
0013-4651

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The al&l reactions and subsequent &znsrnetallarion of ~skannylpropionates is described. We recently reported' that the lithium enolate (2) undergoes clean alkylation reactions generating the stannanes (3) with high levels of asymmeaic induction (d.s. > 99:5). The stannanes (3) serve as useful inter